Which is the weakest intermolecular force, considered as the Van der Waals force, often found in halogens, noble gases and other non-polar molecules?

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SSC Selection Post 2024 (Matriculation Level) Official Paper (Held On: 21 Jun, 2024 Shift 1)
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  1. London dispersion forces 
  2. Ion-dipole forces
  3. Dipole– induced dipole forces
  4. Dipole – dipole forces

Answer (Detailed Solution Below)

Option 1 : London dispersion forces 
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The correct answer is London dispersion forces

Key Points

  • London dispersion forces are the weakest intermolecular forces.
  • These forces are a type of Van der Waals force and are present in all atoms and molecules, but are most significant in non-polar molecules.
  • They arise due to temporary fluctuations in electron density, which create instantaneous dipoles.
  • These instantaneous dipoles induce dipoles in neighboring atoms or molecules, leading to an attraction.
  • Halogens, noble gases, and other non-polar molecules primarily exhibit London dispersion forces.

Additional Information

  • Ion-dipole forces involve an ion and a polar molecule and are generally stronger than London dispersion forces.
  • Dipole-dipole forces occur between polar molecules and are also stronger than London dispersion forces.
  • Dipole-induced dipole forces involve a polar molecule inducing a dipole in a non-polar molecule, and are weaker than dipole-dipole forces but stronger than London dispersion forces.
  • London dispersion forces are significant in determining the physical properties of non-polar substances, such as boiling and melting points.
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