Question
Download Solution PDFThe equilibrium constant for a reaction is not affected by the presence of:
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFCONCEPT:
Equilibrium Constant and Its Dependence
- The equilibrium constant (K) is a measure of the extent of a reaction at equilibrium at a given temperature.
- The equilibrium constant depends on the temperature of the system because it is derived from the Gibbs free energy change (ΔG).
- The relationship between the equilibrium constant and temperature is given by the van 't Hoff equation.
- Other factors, such as pressure, pH, or the presence of a catalyst, do not affect the value of the equilibrium constant directly because K is only a function of temperature.
EXPLANATION:
- A catalyst speeds up the rate of both the forward and reverse reactions equally, without altering the equilibrium concentrations of reactants and products.
- Since the equilibrium constant (K) depends only on the ratio of the concentrations of the products and reactants at equilibrium, the catalyst has no effect on its value.
- Pressure and pH may shift the position of equilibrium (Le Chatelier's Principle), but they do not change the value of K itself.
- Temperature, on the other hand, can change the equilibrium constant because it affects the Gibbs free energy (ΔG).
Therefore, the equilibrium constant for a reaction is not affected by the presence of a catalyst.
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