Question
Download Solution PDFThe transition for which the first derivative of the chemical potential with respect to temperature is continuous but its second derivative of the chemical potential with respect to temperature is discontinuous is classified as:
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFCONCEPT:
Phase Transitions and Classification
- A phase transition occurs when a substance changes from one phase to another (e.g., solid to liquid, liquid to gas) and is characterized by changes in thermodynamic quantities.
- The order of a phase transition is determined by the behavior of the derivatives of the thermodynamic potential (such as chemical potential, Gibbs free energy, etc.) with respect to temperature or pressure:
- First-order phase transitions: The first derivative of the thermodynamic potential is discontinuous (e.g., latent heat).
- Second-order phase transitions: The first derivative is continuous, but the second derivative is discontinuous.
- Zero-order phase transitions: Rare cases where the thermodynamic potential itself is discontinuous.
EXPLANATION:
- In the given question, the transition is described as having the first derivative of the chemical potential with respect to temperature being continuous, but the second derivative is discontinuous.
- This behavior aligns with the definition of a second-order phase transition.
- In second-order phase transitions:
- There is no latent heat involved (no discontinuity in entropy or enthalpy).
- Examples include the transition in superconductors and ferromagnetic materials near critical points.
Therefore, the correct answer is Option 2: Second-order phase transition.
Last updated on Jul 21, 2025
-> DSSSB PGT Answer Key 2025 has been released on 21st July 2025 on the official website.
-> The DSSSB PGT Notification 2025 has been released for 131 vacancies.
-> Candidates can apply for these vacancies between 8th Juy 2025 o 7th August 2025.
-> The DSSSB PGT Exam for posts under Advt. No. 05/2024 and 07/2023 will be scheduled between 7th to 25th July 2025.
-> The DSSSB PGT Recruitment is also ongoing for 432 vacancies of Advt. No. 10/2024.
-> The selection process consists of a written examination and document verification..
-> Selected Candidates must refer to the DSSSB PGT Previous Year Papers and DSSSB PGT Mock Test to understand the trend of the questions.