The d2sp2 hydridisation shows which structure?

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DSSSB PGT Chemistry (Female) Official Paper (Held On: 06 Jul, 2018 Shift 1)
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  1. Otahedral 
  2. Square planar 
  3. Trigonal planar 
  4. Tetrahedral 

Answer (Detailed Solution Below)

Option 1 : Otahedral 
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CONCEPT:

d2sp2 Hybridization

  • Hybridization occurs when atomic orbitals mix to form new hybrid orbitals, which influence the geometry of molecules.
  • d2sp2 hybridization involves the mixing of two d orbitals, one s orbital, and one p orbital from the valence shell.
  • This type of hybridization is characteristic of square planar geometry in coordination compounds.

EXPLANATION:
hybrid orbitals and geometry

  • When a central metal atom undergoes d2sp2 hybridization, the resulting hybrid orbitals arrange themselves in a square planar geometry to minimize electron pair repulsion.
  • This geometry is commonly observed in coordination complexes with a coordination number of 4, where ligands are arranged in a planar square around the central metal atom.
  • An example of a compound showing d2sp2 hybridization and square planar geometry is [Ni(CN)4]2-.

Therefore, the structure resulting from d2sp2 hybridization is square planar.

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