Chemical formula of cryolite is ..........?

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  1. CaF2
  2. NaF
  3. AIF3
  4. Na3AIF6

Answer (Detailed Solution Below)

Option 4 : Na3AIF6
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CONCEPT:

Chemical Formula of Cryolite

  • Cryolite is a mineral that is used in the aluminum extraction process, specifically in the Hall-Héroult process for the electrolytic reduction of alumina (Al2O3) to aluminum.
  • The chemical formula of cryolite is Na3AlF6.
  • Cryolite serves as a flux in the process, reducing the melting point of alumina and improving the efficiency of the aluminum extraction process.

EXPLANATION:

  • CaF2 - This is the formula for fluorite, not cryolite.
  •  NaF - Sodium fluoride, which is incorrect as cryolite contains aluminum and multiple fluoride ions.
  • AlF3 - Aluminum fluoride, which is incorrect since cryolite also contains sodium.
  • Na3AlF6 - This is the correct formula for cryolite, as it contains sodium, aluminum, and fluoride ions in the right proportions.

Therefore, the chemical formula of cryolite is Na3AlF6.

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