Two moles of calcium phosphate on reduction with carbon in the presence of silica resulted in the formation of a phosphorus compound X in 90% yield. The weight of X is (Atomic weight, Ca 40, P 31, Si 28, O 16, C 12, H 1)

  1. 124 g
  2. 111.6 g
  3. 255.6
  4. 198 g

Answer (Detailed Solution Below)

Option 2 : 111.6 g

Detailed Solution

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Explanation: 

2Ca3(PO4)2+10C+6SiO2P4+6CaSiO3+10CO

  • Step 1: Molar masses of the relevant compounds:

    • Molar mass of (Ca3(PO4)2):

      • 3×Ca+2×P+8×O=3×40+2×31+8×16=310g/mol

    • Molar mass of (P4):

      • 4×P=4×31=124g/mol

  • Step 2: Stoichiometric relationship between calcium phosphate and phosphorus ((P4)):

    • From the balanced equation, 2 moles of (Ca3(PO4)2) produce 1 mole of (P4).

    • Therefore, if 2 moles of calcium phosphate are used, we get 1 mole of (P4), which weighs 124 g.

  • Step 3: Account for the 90% yield of the reaction:

    Actual weight of P4=Theoretical weight of P4×Yield=124g×0.9=111.6g

    • Since the yield of the reaction is 90%, we need to calculate the actual amount of (P4) produced:

Conclusion:

The actual weight of phosphorus compound X produced is 111.6 g.

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