Question
Download Solution PDFThe correct sequence of ligands in the order of decreasing field strength is :
- CO > H2O > F- > S2-
- -OH > F- > NH3 > CN-
- NCS- > EDTA4- > CN- > CO
- S2- > -OH > EDTA4- > CO
Answer (Detailed Solution Below)
Option 1 : CO > H2O > F- > S2-
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Detailed Solution
Download Solution PDFExplanation
Ligand Field Strength
- The field strength of ligands is determined by their ability to split the d-orbitals of a central metal ion in a coordination complex.
- This is often described using the spectrochemical series, which arranges ligands in order of their field strength.
- Stronger field ligands cause greater splitting of the d-orbitals, leading to higher energy differences between the d-orbital sets.
- Common order of field strength for some ligands is:
- ( \(CO > CN^- > NO_2^- > en > NH_3 > NCS^- > H_2O > EDTA^{4-} > OH^- > F^- > S^{2-} \))
Conclusion
Based on the given options and the general spectrochemical series, the correct sequence in decreasing order of field strength is CO > H2O > F- > S2-
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