Acetic anhydride is used as -

(i) Acetylating agent

(ii) Dehydrating agent

(iii) Reagent in Perkin reaction

(iv) Methylating agent

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  1. only (i)
  2. only (i) and (ii)
  3. only (i), (ii) and (iii)
  4. only (i), (ii) and (iv)

Answer (Detailed Solution Below)

Option 3 : only (i), (ii) and (iii)
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Detailed Solution

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Concept and Explanation:

  • Uses of Acetic Anhydride: Acetic anhydride is a versatile reagent in organic chemistry.

    • (i) Acetylating Agent: Acetic anhydride is widely used as an acetylating agent to introduce the acetyl group (−COCH3) into molecules. This is a common reaction in the synthesis of esters and amides.

    • (ii) Dehydrating Agent: It acts as a dehydrating agent in many chemical reactions, facilitating the removal of water.

    • (iii) Reagent in Perkin Reaction: Acetic anhydride is used as a reagent in the Perkin reaction, which is a method for synthesizing α,β-unsaturated aromatic aldehydes by the aldol condensation of an aromatic aldehyde with an acid anhydride in the presence of a base.

    • (iv) Methylating Agent: Acetic anhydride is not typically used as a methylating agent. Methylation usually involves reagents that donate a methyl group (−CH3), such as methyl iodide, methyl sulfate, or methyl triflate.

Conclusion:

The correct uses of acetic anhydride are: only (i), (ii) and (iii)

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