The Carbon Carbon bond length is maximum in -

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  1. CH2=CH2
  2. HC≡CH
  3. F1 Priya Teaching 5 11 2024 D28
  4. CH3CH3

Answer (Detailed Solution Below)

Option 4 : CH3CH3
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Detailed Solution

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Concept:

  • Hybridization and Bond Length: The type of hybridization affects bond length. The order of bond length from longest to shortest generally follows: sp3 (single bond) > sp2 (double bond) > sp (triple bond).

  • Bond Length Hierarchy:

    • Single bonds (σ bonds) have the longest bond length.

    • Double bonds (σ and π bonds) have shorter bond lengths than single bonds.

    • Triple bonds (σ and two π bonds) have the shortest bond lengths.

Explanation:

  • CH2=CH2 (Ethene): Contains a double bond between the carbon atoms, indicating sp2 hybridization for each carbon.

  • HC≡CH (Ethyne): Contains a triple bond between the carbon atoms, indicating sp hybridization for each carbon.

  • Benzene: Contains alternating single and double bonds, often described as having a bond length between a single and double bond due to resonance, indicating sp2 hybridization.

  • CH3CH3 (Ethane): Contains a single bond between the carbon atoms, indicating sp3 hybridization for each carbon.

Conclusion:

Considering the hybridization and the bond length hierarchy, the maximum carbon-carbon bond length is found in: CH3CH3

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