Identify A and B in the given chemical reaction sequence : -

19-5-2025 IMG-649 Ankit -88

  1. 19-5-2025 IMG-649 Ankit -89
  2. 19-5-2025 IMG-649 Ankit -90
  3. 19-5-2025 IMG-649 Ankit -91
  4. 19-5-2025 IMG-649 Ankit -92

Answer (Detailed Solution Below)

Option 2 : 19-5-2025 IMG-649 Ankit -90

Detailed Solution

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CONCEPT:

Friedel-Crafts Acylation and Clemmensen Reduction

  • Friedel-Crafts acylation involves the introduction of an acyl group (RCO-) into an aromatic ring using a Lewis acid catalyst like AlCl3.
  • In this reaction, the benzene ring reacts with an acyl chloride in the presence of AlCl3 to form a ketone.
  • The Clemmensen reduction then reduces the ketone to an alkyl group using Zn-Hg and HCl, converting the carbonyl group into a methylene (-CH2-) group.

EXPLANATION:

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  • In the given reaction sequence, compound A is formed by the acylation of benzene with succinyl chloride in the presence of AlCl3, yielding a diketone compound.
  • Compound B is formed by the subsequent Clemmensen reduction, which reduces the carbonyl groups of the diketone to form a cyclic ketone.
  • The correct structures of compounds A and B correspond to option (1) in the given question.

The correct answer is option (1).

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