How much of heat is to be removed from 50 g of water at 50°C to convert it into ice at 0°C? (Latent heat of fusion of ice = 80 cal g–1 and specific heat of water = 1 cal/g/°C)

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  1. 6500 calorie
  2. 650 calorie
  3. 650 J
  4. 6500 J

Answer (Detailed Solution Below)

Option 1 : 6500 calorie
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The Correct answer is 6500 calorie.

Key Points

  • To calculate the total heat removed from water, we need to consider two stages:
    • Cooling the water from 50°C to 0°C.
    • Freezing the water at 0°C into ice.
  • The formula to calculate heat required to cool water is: Q = m × c × ΔT, where:
    • m is the mass of the water (given as 50 g).
    • c is the specific heat of water (1 cal/g/°C).
    • ΔT is the temperature change (50°C - 0°C = 50°C).
  • Substituting the values: Q = 50 × 1 × 50 = 2500 calories.
  • For freezing water into ice, the formula is: Q = m × L, where:
    • L is the latent heat of fusion of ice (80 cal/g).
  • Substituting the values: Q = 50 × 80 = 4000 calories.
  • Total heat removed = 2500 + 4000 = 6500 calories.

Additional Information

  • Latent Heat of Fusion:
    • The latent heat of fusion is the amount of heat energy required to change the state of a substance from solid to liquid (or vice versa) without changing its temperature.
    • For water, it is 80 cal/g, which means 80 calories of heat energy are required to convert 1 gram of ice into water at 0°C.
  • Specific Heat:
    • The specific heat is the amount of heat energy required to raise the temperature of 1 gram of a substance by 1°C.
    • For water, the specific heat is 1 cal/g/°C, which is relatively high compared to most substances.
  • Importance of Cooling and Freezing:
    • Cooling water to 0°C involves removing heat based on the temperature difference and specific heat.
    • Freezing water to ice requires additional heat removal, calculated using the latent heat of fusion.
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