Which of the following fuels detonates readily?

This question was previously asked in
BPSC AE Paper 5 (Mechanical) 2012 Official Paper
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  1. Benzene
  2. Iso-octane
  3. n-heptane
  4. Alcohol

Answer (Detailed Solution Below)

Option 3 : n-heptane
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Detailed Solution

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Explanation:

  • Detonation is a rapid and violent form of combustion due to which strong shock wave propagates into the explosion.
  • It is the spontaneous combustion of the end gas in the chamber.
  • It is generally caused by:
    • Excessive heat
    • Excessive cylinder pressure 
    • Improper ignition timing
  • Octane Number
    • Octane Number is a measure of the quality of petrol.
    • It is the percentage of iso-octane in the mixture of iso-octane and n-heptane which has the same knocking properties as the fuel sample.
    • Iso-octane chemically being a very good antiknock fuel, is arbitrarily assigned a rating of 100 octane number.
    • Normal heptane (C7H18) has very poor antiknock qualities i.e. readily detonates and is given a rating of 0 octane number. So, if normal heptane (C7H18) is present in the fuel then it will create knocking which will result in the auto-ignition. 

Important Points

  • A fuel having higher self-ignition temperature detonates less, n-heptane fuel detonates readily. While iso-octane has little tendency towards detonation.
  • Detonation in petrol engines can be reduced by the addition of a small amount of lead ethide or ethyl fluid into the fuel commonly known as doping
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