In the X-ray diffraction of a set of crystal planes having d equal to 0.18 nm, the first-order reflection is found to be at an angle of 22°. The wavelength of X-rays is: (sin 22° = 0.208)

  1. 0.0749 nm
  2. 0.0374 nm
  3. 0.779 nm
  4. 0.374 nm

Answer (Detailed Solution Below)

Option 1 : 0.0749 nm
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Concept:

Bragg’s Law states that when an X-ray beam are allowed to scatter through a crystalline surface, its angle of incidence θ will reflect with some angle of scattering θ. And when the path difference d is equal to a whole number n, of wavelength.

It can be represented as

2dsinθ  =nλ

Calculation:

Given:

d = 0.18 nm, n = 1, θ = 22°

⇒ 2 × 0.18 × sin 22° = 1 ⋅ λ

⇒ λ = 0.07488 nm

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