Which statements from the list below are false?

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  1. The general formula of alkynes is CnH2n-2 where n is the number of carbon atoms in one molecule of the alkyne.
  2. The unsaturated hydrocarbons are obtained mostly from petroleum by a process called cracking.
  3. An unsaturated hydrocarbon in which the two carbon atoms are connected by a double bond is called an alkene.
  4. The simplest alkene is ethene having the molecular formula C2H4.

Answer (Detailed Solution Below)

Option 2 : The unsaturated hydrocarbons are obtained mostly from petroleum by a process called cracking.
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Detailed Solution

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The correct answer is Option 2.

Key Points

  • Cracking is a process used in the petroleum industry to break down large hydrocarbon molecules into smaller, more useful ones.
  • Cracking is primarily used to produce gasoline, diesel, and other fuels from heavier fractions obtained during the refining of crude oil.
  • Unsaturated hydrocarbons, such as alkenes and alkynes, are not predominantly produced through cracking; they are usually produced through other chemical processes such as dehydrogenation or polymerization.
  • The statement suggesting that unsaturated hydrocarbons are mostly obtained from petroleum by cracking is false because cracking is not the primary method for producing unsaturated hydrocarbons.

Additional Information

  • Alkynes:
    • Alkynes are hydrocarbons with at least one carbon-carbon triple bond.
    • The general formula for alkynes is CnH2n-2, where n is the number of carbon atoms in the molecule.
  • Alkenes:
    • Alkenes are hydrocarbons with at least one carbon-carbon double bond.
    • The simplest alkene is ethene (C2H4).
  • Unsaturated Hydrocarbons:
    • Unsaturated hydrocarbons contain double or triple bonds between carbon atoms, making them more reactive than saturated hydrocarbons.
    • Examples include alkenes (double bonds) and alkynes (triple bonds).
  • Cracking Process:
    • Cracking is a major industrial process in petroleum refining used to convert heavy hydrocarbon fractions into lighter products like gasoline and diesel.
    • It involves breaking long-chain hydrocarbons into shorter ones, which are more valuable as fuel.
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