What kind of bond is between the hydrogen atoms in a hydrogen molecule?

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MP Excise Constable Official Paper (Held On: 26 Feb 2023 Shift 1)
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  1. Pi bond
  2. Sigma bond
  3. Ionic bond
  4. Metallic bond

Answer (Detailed Solution Below)

Option 2 : Sigma bond
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The correct answer is Sigma bond.

Key Points

  • A sigma bond (σ bond) is the strongest type of covalent chemical bond.
  • In a hydrogen molecule (H2), the bond between the two hydrogen atoms is a single sigma bond.
  • Sigma bonds are formed by the head-on (end-to-end) overlap of atomic orbitals.
  • The electron density in a sigma bond is concentrated directly between the nuclei of the bonding atoms.

Additional Information

  • Types of Covalent Bonds:
    • Sigma Bond (σ bond): Formed by the head-on overlap of orbitals, found in single bonds.
    • Pi Bond (π bond): Formed by the side-by-side overlap of p orbitals, found in double and triple bonds.
  • Overlap of Orbitals:
    • Sigma bonds can involve s-s, s-p, or p-p orbital overlaps.
    • Pi bonds usually involve p-p orbital overlaps.
  • Bond Strength:
    • Sigma bonds are generally stronger than pi bonds due to the direct overlap of orbitals.
    • In multiple bonds (double or triple), one bond is a sigma bond, and the others are pi bonds.
  • Molecular Orbital Theory:
    • Describes the formation of covalent bonds in terms of the combination of atomic orbitals to form molecular orbitals.
    • Sigma molecular orbitals result from the constructive interference of atomic orbitals.
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