Question
Download Solution PDFThe srtructure of A in the following reaction is
Answer (Detailed Solution Below)
Detailed Solution
Download Solution PDFConcept:
- The [2+2] cycloaddition reaction involves the addition reaction of two diene molecules to give a cyclic compound. The [2+2] cycloaddition reaction between two alkenes is a photochemically allowed process.
- An example is shown below:
- The [2+2] cycloaddition reaction between an alkyne and an alkene is photochemically allowed but thermally forbidden because of symmetry mismatch between the overlapping orbitals.
- The intramolecular aldol reaction is the condensation reaction of two aldehyde groups or ketone groups in the same molecule in the presence of a base.
- An example is shown below:
Explanation:
- The reaction pathway is shown below:
- From the above reaction, we see that the first step involves the [2+2] photochemical cycloaddition reaction between an alkyne and an alkene to give a cyclic compound followed by an ozonolysis reaction.
- In the last step of the reaction, it undergoes an intramolecular aldol reaction to give the desired product.
Conclusion:
Hence, the structure of A in the following reaction is
Last updated on Jul 19, 2025
-> The CSIR NET June 2025 Exam Schedule has been released on its official website. The exam will be held on 28th July 2025.
-> CSIR NET City Intimation Slip 2025 has been released @csirnet.nta.ac.in.
-> The CSIR UGC NET is conducted in five subjects -Chemical Sciences, Earth Sciences, Life Sciences, Mathematical Sciences, and Physical Sciences.
-> Postgraduates in the relevant streams can apply for this exam.
-> Candidates must download and practice questions from the CSIR NET Previous year papers. Attempting the CSIR NET mock tests are also very helpful in preparation.