Answer (Detailed Solution Below)
Option 2 :
India's Super Teachers for all govt. exams Under One Roof
FREE
Demo Classes Available*
Enroll For Free Now
Detailed Solution
Download Solution PDFCONCEPT:
Formation of Grignard Reagent and Subsequent Cyclization
- When an alkyl halide is treated with magnesium (Mg) in dry ether, a Grignard reagent (RMgBr) is formed.
- The Grignard reagent is highly reactive and can undergo intramolecular reactions, especially when a halide group is present on the same molecule.
- This can lead to the formation of cyclic structures if the conditions favor such an intramolecular attack.
EXPLANATION:
- In this reaction, the presence of two bromine atoms in close proximity leads to the formation of two Grignard reagents.
- One of the Grignard reagents can perform an intramolecular attack on the other carbon atom bearing the second bromine, leading to the elimination of MgBr2.
- This intramolecular reaction results in the formation of a three-membered cyclopropane ring as the major product, as shown in option (2).
India’s #1 Learning Platform
Start Complete Exam Preparation
Daily Live MasterClasses
Practice Question Bank
Video Lessons & PDF Notes
Mock Tests & Quizzes
Trusted by 7.2 Crore+ Students