A container has two chambers of volumes V1 = 2 litres and V2 = 3 litres separated by a partition made of a thermal insulator. The chambers contain n1 = 5 moles and n2 = 4 moles of ideal gas at pressures p1 = 1 atm and p2 = 2 atm, respectively. When the partition is removed, the mixture attains an equilibrium pressure of:

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  1. 1.3 atm
  2. 1.6 atm
  3. 1.4 atm
  4. 1.8 atm

Answer (Detailed Solution Below)

Option 2 : 1.6 atm
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Correct option is: (2) 1.6 atm

Before partition

after partition removed

P1V1 + P2V2 = P(V1 + V2)

⇒ 1 × 2 + 2 × 3 = P × (2 + 3)

⇒ 8 / 5 = P

⇒ P = 1.6 atm

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