Question
Download Solution PDFA compound X, of boron reacts with NH3 on heating to give another compound Y which is called inorganic benzene. The compound X can be prepared by treating BF3 with Lithium aluminium hydride. The compounds X and Y are represented by the formulas.
- B2H6 , B3N3H6
- B2O3, B3 N3H6
- BF3, B3N3H6
- B3N3H6 , B2H6
Answer (Detailed Solution Below)
Option 1 : B2H6 , B3N3H6
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Detailed Solution
Download Solution PDFCorrect answer: 1)
Concept:
- Binary compounds of B with H are called boron hydrides or boranes.
- Lithium aluminum hydride is a strong reducing agent with the formula
LiAlH4 and also known as LAH. Lithium aluminium hydride as having a strong reducing agent can reduce almost all the ketones into alcohol. - A mixture of diborane with air or oxygen catches fire spontaneously producing a large amount of heat.
- Diborane has a higher heat of combustion per unit weight of fuel than most other fuels.
- It is therefore used as rocket fuel.
Explanation:
- A compound X, of boron, reacts with NH3 on heating to give another compound Y.
- Compound Y is called inorganic benzene because it has a similar structure to benzene and it is not organic in nature.
- The compound X can be prepared by treating BF3 with Lithium aluminum hydride.
Conclusion:
Thus, the compounds X and Y are represented by the formulas: (X)B2H6, (Y)B3N3H6.
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